Paltrow and Williams both appeared in the 1991 classic Hook, with Paltrow as a young Wendy Darling opposite Williams as Peter Pan — but as she told Poehler, she didn't actually work with Williams for the role. But when Affleck worked with him for Good Will Hunting, she got to know him more.

So, in a sweet plot twist, performing the scenes didn’t prove to be as awkward as Paltrow assumed they’d be. What also seemed to add to her comfort was the fact that she was working with a skilled young actor in Chalamet. The Talented Mr. Ripley star went on to sing the praises of her scene partner:

Gwyneth Paltrow has opened up about filming intimate scenes with her much younger Marty Supreme co-star, Timothee Chalamet, revealing the experience was far less awkward than she anticipated. Gwyneth Paltrow talks about Timothee Chalamet scenes During a recent Q&A,

Gwyneth Paltrow reflected on the moments she felt lost in her acting career, including when her kids Apple and Moses—whom she shares with ex-husband Chris Martin—went off to college.

Isaac Mizrahi exclusively tells PEOPLE about his reunion with Gwyneth Paltrow while playing her character’s publicist in 'Marty Supreme.' "I used to make clothes for Gwyneth in the '90s," he says.

Gwyneth Paltrow said she "really struggled" when her kids, Apple Martin, 21, and Moses Martin, 19, flew the nest.

Gwyneth Paltrow shared she lost out on a movie role after she and ex-husband Chris Martin announced their divorce, which they notably phrased as “conscious uncoupling,” in 2014.

Gwyneth Paltrow had some misgivings about her sex scene with Timothée Chalamet in the comedy-drama "Marty Supreme."

Amy Poehler had her eyes wide shut for this movie. The actress, 54, accidentally mistook Nicole Kidman for Gwyneth Paltrow in the 2003 film “Cold Mountain.” “‘Cold Mountain.’ How cold was the mountain?” Poehler teased to the Goop founder, 53, on Tuesday’s episode of her “Good Hang” podcast.

One of the A-list celebrities to pen a tribute was none other than Oscar-nominated actress Florence Pugh, who went viral for wearing a sheer Valentino dress that began the "free the nipple" movement. This even led her to becoming the face of the brand. Pugh took to Instagram story to write the following message: